Don't try and give your client machines IP addresses -- make use of the stateless address auto-configuration and just set up zebra or radvd on your gateway. See Simple IPv6 HOWTO for a quick introduction.
Make sure IPv6 is either compiled into the Kernel, or compile it as a module and load it by way of modprobe ipv6.
For debugging, you'll want to install traceroute6 and ping6; on Debian, apt-get install iputils-tracepath iputils-ping.
A cheap way of installing IPv6 under Linux is to grab a 6to4 script, put it in your /etc/init.d directory, and set it to run on boot. That's it, you're done. (See 6to4 for a more involved explaination as to what this script does.)
If you want a statically assigned address, you'll probably need to use a tunnel broker.
Start up a command prompt and type ipv6 install
The following page may be of some assistance: Microsoft IPv6 Technology Preview for Windows 2000
GENERIC supports it by default, but otherwise compile support into your kernel with the following options
options INET6 device gif # IPv6 and IPv4 tunneling device faith # for IPv6 and IPv4 translation device stf # 6to4 IPv6 over IPv4 encapsulation
See IFM's configuration wizard
Part of CategoryNetworking
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